DIY silver solder: physical and chemical properties


Silver solder is constantly used for industrial production and at home, because it is of the highest quality.
However, its cost is quite high, because it contains precious material. This is why people often try to make this solder themselves. However, this can only be done by those who have specialized knowledge in this area, because it is necessary to make a material that will have all the necessary characteristics and properties. Silver in its pure form is a rather expensive metal, so it is used for solder in rare cases; it is mainly needed for jewelry production. The material has a soft structure, so to ensure a high-quality connection, it is necessary to add other materials to the alloy, for example, aluminum, cadmium, zinc, nickel or copper. When pure silver is combined with copper and zinc, the melting of the metal will become significantly higher, which has a good effect on soldering parts. The seams are of high quality and durable. If there is about 10% or more silver in the material, then the seams become very plastic and are perfectly processed. This option is excellent for soldering steel materials.

With a pure silver content of about 25%, the material efficiently solders brass workpieces. The resulting surface is neat and looks attractive.

Very often, solders are produced in the form of continuous sheets. Before work, it must be carefully divided into strips of about 2 mm in size, but the width can be made at your own discretion, it depends on how the material will be used. Gap soldering in this way produces the highest quality. After use, the seams tolerate various vibrations well and do not deteriorate. Parts may even be deformed or subjected to physical stress, but the connection remains intact and sealed for maximum time.

Chemical composition of the alloy for joining materials

Pure silver is a soft metal and is therefore not suitable for work.
Mostly, craftsmen use mixtures that contain zinc, nickel, aluminum, copper, and cadmium. In addition to silver, silver solders also contain zinc and copper. A seam made with this composition is strong and durable. Compounds of silver, copper, zinc have a high melting ability. They are used for silver solder. To control its percentage composition, GOST 19746 74 was developed. Solders, silver grades, are always indicated in the instructions for the products. The soldering seam obtained in this way is durable.

Modern soldering processes involve the use of silver solder, which, when connecting nodes, is suitable for step soldering. Such work requires the use of an alloy that can withstand temperatures of 600°C.

The solder contains ingredients such as 30% silver, 20% copper, 16% zinc, 33% cadmium. The alloy is very brittle and is intended for soldering materials that are not subject to vibration. The composition with the amount of silver increased to 52% is very fluid, but withstands loads well during multi-stage stages of soldering materials.

Silver solder has high strength, is resistant to corrosion in aggressive environments, has a low melting point, and high thermal conductivity. During operation, it completely fills the gap between the parts being soldered and fits well on the metal surface.

When working, you need to make sure that the solder completely fills the gap between the parts.

An alloy of 28.5% copper of the PSr-72 grade has high ductility. When working on creating solder with your own hands, you should remember that its melting point with copper decreases when alloyed with lithium. The resulting alloy is used for soldering steel materials that are resistant to corrosion. To reduce the melting temperature of the solder, tin is added to it in an amount of 35 to 70%. The resulting alloy allows you to solder various materials, avoiding the formation of cracks.

Where can I get tin?

I need a certain amount of tin - I wanted to cast it here in my spare time. anything.

I just can’t even imagine where they get it.

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Chemical composition of the alloy for joining materials

The process technology is based on the use of silver solder intended for step soldering. Considering that the solder must withstand temperatures up to 600 °C, its components are: 33% cadmium, 30% silver, 16% zinc, 20% copper. The composition is quite fragile and cannot withstand vibrations. By increasing the amount of silver to 52%, a fluid mixture is obtained that can withstand multi-stage soldering.

The creation of homemade solder is mainly for the private sector. Do-it-yourself silver solder is often made in order to carry out step soldering, when it is necessary to solder several layers of metal, since it is necessary to obtain a layer of great thickness, which cannot be created at one time.

To create such a material, you need to take 30% silver. Additional elements will be cadmium, which should be 33%, zinc - 16%, and copper - 20%. It is advisable not to use this alloy in places that are subject to strong vibrations and shocks, as it is brittle and can be destroyed under mechanical stress.

Silver solder

An ancient recipe for cooking silver solder

Let's try to figure out how to make silver solder at home. There are several options for its manufacture, each with its own nuances. To obtain the alloy, you will need a coin (fifty kopecks) from 1924, as well as five kopecks from 1962. For work you need: ingus, silver, gas burner, spoon.

Making silver solder begins with melting the precious metal. Then a five-kopeck coin is added. To ensure complete mixing, roll the mixture onto a spoon. The final result of mixing depends on the duration of this process. The disadvantage of this technology is the burnout of the chemical components needed for solder.

It is most convenient to heat solder on a gas burner.

  • silver;
  • spoon (not tablespoon);
  • ingus;
  • gas-burner.

At the beginning of the work, silver is melted in a spoon. Add a five-kopeck coin to the resulting melt and roll the mixture over a spoon for better mixing. The longer the spoon is rolled, the better the mixing process occurs. But there is one significant drawback: many components necessary for solder burn out.

Then the master who makes the alloy with his own hands pours it into ingus and rolls it out without annealing. The resulting solder is of high quality: 10 g refers to the 900th sample.

When soldering, it is very important to prepare fresh flux, which will ensure high-quality work. It is necessary to carefully monitor the size of the flame in the burner: a soft, not very hot fire in the form of a broom will ensure a high-quality seam.

For work, hard solders are used, which contain: 80 Ag, 16 Cu, 4 Zn, 75 Ag, 22 Cu, 3 Zn. Soft solders include: 65 Ag, 20 Cu, 15 Zn.

To obtain light silver solder used in repairing products, you need to prepare: 7 parts silver, 2.8 parts brass, 0.35 parts zinc. It is important to clean the brass from the oxide film before starting work. To obtain 10 g of solder, 999 silver is melted. After obtaining the liquid composition, add brass and mix the contents in a spoon.

  • sandpaper;
  • spoon;
  • gas burner;
  • mixing spatula;
  • folds;
  • scissors;
  • scales.

Pure silver is not used for solder, as it is too expensive a metal.

  • silver;
  • brass;
  • pure zinc;
  • borax, which is added to the molten composition.

Sometimes pure zinc is not added: it is better to use its alloy with brass or copper. Zinc is added to the solder, wrapped in silver foil.

How to prepare flux?

Reliable soldering and welding of silver (including in jewelry) is carried out using borax as a flux in the form of a concentrated aqueous solution. This flux can be prepared in the following order. Distilled water is poured into the dry borax powder, and the mixture is slowly heated until the powder is completely dissolved. The cooled solution crystallizes. The resulting sediment is ground with a mortar and diluted with water to the consistency of thick sour cream. If there is a lot of water, then after settling it peels off from the solution itself and this excess is carefully drained. The prepared composition can be used as a high-temperature flux (use temperature from 500 to 900ºС) when soldering silver.

If for some reason a homemade flux turns out to be ineffective, then a ready-made flux of increased activity, brand PV 209, is recommended. It contains boric anhydride (up to 35%), potassium fluoride (up to 42%) and potassium tetraborate (up to 23%). This product is diluted with water or glycerin to a convenient consistency.

Engineering works

For technical work, silver solders are used containing up to 80 parts of silver, 16 parts of copper, 4 parts of zinc. Of interest are jewelry silver solders, the composition of which is: 2.8 parts brass, 7 parts silver, 0.2 parts zinc. Before starting work, the brass is cleaned of the oxide film. To obtain 10 grams of such solder, 999 silver is melted.

Brass is added to the liquid metal and mixed in a spoon. After complete melting, the mixture is combined with zinc, and the resulting composition is rolled. Next, the rolled sheet is cut with scissors and weighed on a scale. For effective work you need: a spoon, sandpaper, a gas burner, scales, folds, a stirring spoon.

  1. Before you start soldering silver, you should prepare the product made from it for work, namely, clean it of contaminants (a degreaser is suitable for this purpose). A thin layer of flux is applied to the treated surface of the product with a brush.
  2. The parts that need soldering are then placed on the brick. To securely fix the elements, you need to use clamps and nichrome wire.
  3. A piece of solder is placed on the part that needs soldering. How to take a fragment: you need to take a strip and use wire cutters to cut off a piece measuring 2 by 2 millimeters.
  4. Take a gas burner and place it on the side of the decoration. The area being treated is heated evenly, but as soon as the flux melts, the flame should be intensified and continued to work until a seam is formed.
  5. After soldering, the product should be cleaned of flux and excess solder. Sandpaper is suitable for this purpose.
  6. Then the decoration should be dipped into a container of water, and then into an etching solution. If the solution gets on your skin, wash it off immediately with water.

During work, care should be taken to comply with personal safety regulations. First of all, it is necessary to ensure access to air in the work area - just open the window. You should work in a denim apron (denim is highly flammable) and safety glasses.

Useful tips

To perform stainless steel soldering efficiently, you should use the recommendations of experienced specialists.

  • The power of a soldering iron, which must effectively heat the metal being joined, is in the range of 60–100 W, but it is better to opt for a 100-watt device. To solder large parts, such as stainless steel pipes, you will need a gas torch rather than an electric soldering iron.
  • When choosing an electric soldering iron, it is better to opt for models equipped with tips that do not burn.
  • The most economical and universal type of solder, which makes it possible to obtain high-quality connections for stainless steel products, is tin-lead rods. If you are soldering dishes that will come into contact with food or liquids, it is better to use pure tin as solder, which does not contain harmful impurities.
  • The room in which soldering work is carried out must be well ventilated.
  • When performing soldering, be sure to use personal protective equipment so as not to harm your health.

Melting solder

By melting the metals that are part of the mixture, silver solder for steel is obtained in a crucible. Place the gel in the forge, having prepared special equipment: borax, a container with water, a coal mixture, an iron hook, a crucible. First you need to melt the refractory metals, and then low-melting metals are added to the mixture.

To make high-quality solder with your own hands, the work must be divided into two stages. First, the crucible is removed from the furnace and the metal is combined in a container filled with water. As a result, fine-grained drops of solder appear. They are dried, then melted again, covered with borax. Once the metal is completely melted, it is poured into special molds. After hardening, the bars or tiles are rolled into thin strips. For subsequent use, they are cut on a lathe into thin wire.

By melting the metals that make up the alloy in a crucible, silver solder is obtained. The crucible is placed in a furnace or the components are melted using a blowpipe. Before work you need to prepare the equipment:

  • crucible;
  • wooden stick or iron hook;
  • borax;
  • charcoal mixture;
  • container with water.

Solder components are melted using borax. The order of the operation is observed: refractory metals are melted first, then low-melting metals are added.

The solder components are melted using borax.

To make solder with your own hands, liquid metals are constantly stirred in a crucible with a wooden rod or an iron hook. To create higher quality solder, the entire process is divided into two stages. The crucible is pulled out of the furnace, and the metal is combined in a container with water. Fine-grained drops are formed, which are dried and melted a second time, covered with borax on top.

After complete melting, the metal is poured into molds. The frozen tiles or bars are rolled into strips, which are crushed on a lathe.

For technical soldering of silver objects, alloys consisting of metals are suitable: 20% copper 80% silver, 4% tin 48% brass. When soldering steel with silver solder, the phase diagram between copper and silver is taken into account.

Features of silver soldering

Soldering with silver solder at home also involves the reverse process - the transformation of liquid metal into a solid state. First, it is important to completely melt the silver, then it is cast into the ingus. All work is divided into three stages: making a spoon - a melting pot, adding flux, placing the charge in the spoon, melting the starting material, placing it in the ingus.

Place a small cardboard rectangle at the bottom of the spoon, then a slightly larger plate so that it wraps around the edges of the spoon. Then the cardboard sheets are fried with high quality. The stock must be concave to achieve the desired result. The process of melting solder at home is lengthy, so you will have to be patient. Sorting of the charge is carried out on jewelry scales. The master will need the following materials:

  • electronic jewelry scales;
  • 20 g of 916 silver scrap;
  • 875 silver scrap;
  • pure silver (12 grams);
  • borax;
  • metal for solder;
  • gas-burner

Silverware repair

Beautiful chains, bracelets, earrings, forks, spoons, silver glass holders decorate a person’s life. But over time, products made of precious metal break down and need repair and restoration. To perform such work you will need silver solder. For 925 standard, you can make it yourself, using the advice of professional jewelers.

For the work you will need the following materials and tools: regular and irregular-shaped soldering irons, solder casting, scrap silver. The easiest way to repair a broken chain is to take it to a jeweler. But if you wish, you can cope with the problem at home, saving money.

To perform such actions, it is important to have information about the physical and chemical characteristics of the material. The melting point of silver is 960 degrees Celsius. From the jewelers' point of view, this is an average figure. For example, copper can melt at 1083ºC, gold melts at 1063ºC.

Depending on the components that make up the silver, their temperature will vary. In order to accurately find out the characteristics of the alloy, you can use technical reference books. Marking of silver solders implies a sequence of Russian letters and numbers. The numbers characterize the percentage of noble metal in the solder.

To repair a silver product, you need to prepare a soldering iron and clean the surface of the product. Silver solder allows you to make strong, tight seams that are resistant to corrosion. When repairing jewelry, solder containing more than 70 percent silver or a special soldering paste is used.

A few recommendations

Do not use too much solder to avoid lumps. If they do form, they must be removed with a nail file. If an acid solution spills on clothing or skin, immediately rinse the area with plenty of cold water.

Soldering of any metal is based on knowledge of its physical and chemical properties. This also applies to silver. The transition temperature of this metal from solid to molten state is +960 degrees. This is an ideal indicator.

In practice, when soldering, you have to deal with alloys, and the melting temperature here directly depends on the components, as well as their percentage. Soldering silver requires care, and before starting it, it’s a good idea to practice on inexpensive products.

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