F-64 flux for aluminum and other light alloys

Fluxes for aluminum

Soldering aluminum is a rather complex technological process. In addition to the oxide film on the surface of aluminum, the process is complicated by the need to expose it to higher temperatures than when soldering copper. However, aluminum can be soldered because special fluxes have been developed for this purpose.

The main task of flux for low-temperature soldering of aluminum is to dissolve the oxide film, which interferes with the normal spreading of solder and joining of parts. For soldering aluminum, only active fluxes containing acid are used. Rosin and other similar inactive fluxes are absolutely not suitable for these purposes.

Flux composition for aluminum

The main components of active fluxes for soldering aluminum at temperatures below 300 degrees are organic acids and their amides, as well as triethanolamine. The most active acids are oleic, elaidic, formic and acetic acid.

This is due to the fact that the activity of all of the above acids increases with increasing temperature. Therefore, by acting on Al2O3 oxide, they are able to completely destroy it, which will allow the solder to adhere normally to the surface of the aluminum parts being soldered.

Soldering flux 34-A

Activity temperature range: 420 – 620°C (no specifications in the specifications)

For solders: medium-melting solders based on aluminum alloys with silicon and zinc, such as solder 34-A (no specifications in the specifications)

For materials: aluminum and its alloys (not containing more than 1.5% magnesium - there are no characteristics in the specifications)

Physical state: powder

Application methods: pour flux powder, dip into a flux solution in water

Heating methods for soldering: torch flame, oven

Solvents: water

Removing flux residues: washing with hot water

Composition: NaF - 10±1%, LiCl - 32±3%, ZnCl2 - 8±2%, KCl - 50±3%

Complies with TU 48-4-229-87

Flux can be applied in various ways, each having its own advantages and disadvantages. It is necessary to take into account the extreme hygroscopicity of the flux, its tendency to form lumps in the presence of moisture and “spread” when exposed to open air.

It is convenient to slightly warm up small parts and sprinkle them with flux (dip them into the flux), taking advantage of the effect of the flux “sticking” to the heated surface. Wet flux will not stick to a heated surface.

You can sprinkle parts covered with a film of water with flux (dip them in flux) to achieve “sticking”. The prepared surfaces of parts for soldering should be well wetted with water.

Less commonly, in mass production (with a hint of mechanization), they use flux mixing in water and then applying it to the parts by dipping. All flux components are insoluble in water and are suspended in solution. The flux must be constantly stirred to ensure uniform distribution of the components throughout the volume. Dilution must be done extremely carefully, adding flux in small portions and mixing thoroughly. Dissolution occurs with extreme heating! The solution may boil and cause burns!!! It is necessary to wait until the mixture cools before adding flux again. The solution is not intended for long-term storage.

All the described methods are not universal and are designed for highly qualified and experienced soldering workers.

Suitable for soldering in furnaces and torches, except oxygen-acetylene ones due to reduced flux activity.

Soldering aluminum has many difficulties associated with the pronounced characteristics of this metal. An extremely chemically active metal that has a mechanically and chemically resistant film of aluminum oxide in the air, protecting it from chemical interactions with surrounding substances. At the same time, it has high thermal conductivity.

When performing flux soldering, it is necessary to remove the persistent oxide film and protect the surface from oxidation. This is achieved by the fact that the flux (flux 34-A) when heated destroys and dissolves aluminum oxide, while metallic zinc is deposited on the surface, which, together with the flux coating, protects the aluminum. Therefore, when soldering, you need to carefully monitor the integrity of the flux coating.

To ensure uniform spreading of solder, it is necessary to ensure uniform heating in the soldering area. It is necessary to take into account the large heat dissipation from the soldering zone through aluminum parts. Solder spreads better in the direction of increasing heat; this must be taken into account to obtain a fillet transition of solder between parts. Therefore, when heated with a gas burner, the flame should “wash” the soldering zone and some part of the parts adjacent to it. It is necessary to use the middle part of the flame, which has reducing or neutral properties, in contrast to the final oxidizing part, which has a higher temperature. An oxidizing flame can dramatically reduce flux activity! To compensate for the uneven heating of parts being soldered that differ in thickness and weight, the burner flame must be shifted towards a more massive part. When overheated and heated for a long time, aluminum strongly dissolves in the solder, which leads to poor-quality soldering.

The surface of the parts to be soldered must be degreased. “Light” solvents such as acetone give good results. If the surface has not been mechanically treated, it must be etched to remove most of the oxide film in appropriate solutions.

Flux residues are removed by boiling in water or washing with hot water and wiping with a hair brush.

Flux brands for aluminum soldering

Flux F59A - intended for low-temperature soldering of aluminum, as well as AMts alloy with copper and steel, at temperatures from 150 to 320 degrees.

Flux F61A - in addition to soldering aluminum, it is intended for soldering parts made of galvanized iron, copper and beryllium bronze. The temperature for working with flux, as in the previous case, is 150-320°C.

Flux F54A - consists of 82% triethanolamine. This flux is also intended for soldering aluminum and its alloys at home.

Flux F64 - suitable for soldering aluminum and duralumin.

This version of the flux for aluminum is somewhat reminiscent of the LTI-120 soldering flux, which is intended for soldering copper, nickel and carbon steel. When F-64 flux is applied to the surface of aluminum parts, and under the influence of high temperatures, it is able to destroy the durable film of aluminum oxide, thereby cleaning the metal for normal spreading of solder.

All of the above fluxes are suitable for soldering aluminum. Well, you can always find out how to solder wires on the website.

Hardwired

Purpose of flux

BrandAppearanceSolderable metal or metal coatingSolders usedPurpose
Rosin grade ACopper; silver, tin, zinc, tin-lead, tin-bismuth, gold coatings Tin-lead, tin-lead-cadmium (at soldering temperatures above 220°C), silver PSr1.5 and PSr2Manual and mechanized soldering and tinning of mounting elements and other surfaces. Preservation of the product to preserve solderability under warehouse storage conditions.
FKSp (FKEt)Light brown liquidSameSameThe same, as well as soldering of conductors with insulation in the form of tubes or enamel insulation, products with increased requirements for insulation resistance
FCDTDark brown liquidCopper; silver, tin, tin-lead, tin-bismuth, gold coatings Tin-cadmium-indium, tin-lead, tin-lead-bismuth, tin-lead-cadmium, indiumManual and mechanized soldering and tinning of mounting elements and other surfaces.
LTI-120Dark brown liquid with slight sedimentCarbon steel, copper and its alloys, nickel and its alloys; tin, silver, cadmium, zinc, tin-lead, tin-bismuth coatings Tin-lead, silver PSr1.5 and PSr2Manual and mechanized soldering and tinning of mounting elements that do not have insulation in the form of tubes on the terminals, and other surfaces in widely used products.
FGSp, FSkSp, FSkPsFGSp, FSkSp – colorless liquid; FSkPs – homogeneous paste of light yellow color Copper and its alloys, nickel and its alloys; tin, silver, cadmium, zinc, tin-lead, tin-bismuth coatings Tin-lead, tin-lead-bismuth, tin-lead-cadmiumManual (FSkPs and FSkSp) and mechanized soldering and tinning of mounting elements that do not have insulation on the terminals in the form of tubes and other metal surfaces in widely used products
FCSYellow liquidCopper; tin, silver, cadmium, zinc, tin-lead, tin-bismuth coatings Tin-lead, tin-lead-bismuth, tin-lead-cadmiumManual and mechanized soldering and tinning of mounting elements and other metal surfaces in consumer products
FDGLColorless thick liquid. At soldering temperature – brown SameTin-leadManual and mechanized soldering and tinning of consumer products. Group soldering by immersion in soldering flux at a temperature of 220–250°C and melting of electrolytically tin-coated parts before soldering
FCAColorless liquidCopper and its alloys (including BrB), carbon and stainless steels, nickel and its alloysTin-lead and low temperature silverPre-tinning (mechanized and manual) and soldering of products, subject to complete removal (using neutralizing solutions) of flux residues after soldering, except for mounting connections
FDFsColorless liquidSteel, chromium-nickel alloys (nichrome, permalloy, superinvar, kovar, invar), copper and its alloysTin-leadManual and mechanized soldering and tinning of products, except for mounting connections
ZhZ-1-AP,
ZhZ-2-AP
Viscous dark brown liquidTin-leadProtection of the molten solder surface from oxidation in mechanized soldering installations
284, 209White powderCopper and its alloys, stainless and structural steels, heat-resistant alloysSilverSoldering of electronic components and various structures using gas-flame heating and in furnaces
200White powderStainless and structural steels, heat-resistant alloysBrass and solders with a melting point of 850–1000°CSoldering of electronic components and various structures using gas-flame heating and in furnaces
34A, F370AWhite powderAluminum and its alloys, except alloys with magnesium content above 3%AluminumSoldering of electronic components
16VKAluminum and its alloysAluminumSoldering of electronic components. Group soldering of components by immersion in a salt bath

Flux composition. Removing flux residues

Brand Composition (weight) Removing flux residues after soldering
Component%
FKSp (FKEt)Pine rosin10 – 60 Ethyl alcohol or alcohol-gasoline mixture 1:1
Ethyl alcohol or ethyl acetate90 – 40
FCDTPine rosin10 – 20
Dimethylalkylbenzyl ammonium chloride (kitamine AB)0,1 – 3,0
Tributyl phosphate0,01 – 0,10
Ethyl alcohol or ethyl acetate89,89 – 76,90
LTI-120Pine rosin20 – 25
Diethylamine hydrochloride3 – 5
Triethanolamine1 – 2
Ethanol76 – 68
FGSSpHydrazine hydrochloride2 – 4 Hot running water (70±10°C) or alcohol-gasoline mixture 1:1
Ethylene glycol or glycerin25 – 50
Ethanol73 – 46
FSkSpSemicarbazide hydrochloride2 – 4
Ethylene glycol or glycerin25 – 50
Ethanol73 – 46
FSkPsSemicarbazide hydrochloride3 – 5
Glycerol70 – 58
Polyox-100 or Polyox-11527 – 37
FCSSalicylic acid4,0 – 4,5 Alcohol-gasoline mixture 1:1
Triethanolamine1,0 – 1,5
Ethanol95 – 94
FDGLDiethylamine hydrochloride4 – 6 Hot running water (70±10°C)
Glycerol96 – 94
FCAZinc chloride45,5 Hot running water (70±10°C) and neutralizing reagents
Ammonium chloride9
Water45,5
Zinc oxide hydrateBefore precipitation occurs
FDFsDiethylamine hydrochloride20 – 25 Hot running water (70±10°C) or alcohol-gasoline mixture 1:1
Ethylene glycol60 – 50
Phosphoric acid (specific gravity 1.7)20 – 25
ZhZ-1-APCylinder oil “52” or “KS-19”79 – 81 Alcohol-gasoline mixture 1:1, trichlorethylene, acetone
Organosilicon liquid PFMS-616 – 17
Oleic acid4,9 – 1,8
Antioxidant NG-22460,1 – 0,2
ZhZ-2-APCylinder oil “52” or “KS-19”58,52 – 69,75
Organosilicon liquid PFMS-621,65 – 10,66
Cottonseed oil11,0 – 10,64
Oleic acid8,79 – 9,02
Antioxidant NG-22460,04 – 0,03
284Boric anhydride23 – 27 Hot running water (70±10°C) and cold running water
Potassium fluoride33 – 37
Potassium borofluoride-hydrogen44 – 36
209Boric anhydride33 – 37
Potassium fluoride40 – 44
Potassium borofluoride-hydrogen27 – 19
200Boric anhydride70 – 62 Hot flow and neutralizing reagents
Sodium tetraborate (borax)17 – 21
Calcium fluoride13 – 17
34APotassium chloride56 – 44
Lithium chloride29 – 35
Zinc chloride6 – 10
Sodium fluoride9 – 11
F370APotassium chloride51 – 46
Lithium chloride36 – 39
Sodium fluoride4 – 5
Cadmium chloride9 – 10
16VKSodium chloride12
Potassium chloride44
Lithium chloride34
Eutectic (aluminum fluoride – 54%, potassium fluoride – 46%)10

Table 3 influence of flux residues on insulation and their corrosive effect

Brand Effect of flux residues on insulation resistance Corrosive effect of flux residues
for copperfor silver platingon tin-lead coatingfor nickel coating
FKSp (FKEt), FKDTdo not affect do not provide
LTI-120, FGSp, FSkSpreduceprovide do not provide
FSkPsreduceprovidedo not provideprovidedo not provide
FCSreducehave a weak do not provide
FDGLreduceprovidehave a weakdo not providen/a
FDFsreduceprovidedo not providedo not provideprovide
FCAreduce provide
ZhZ-1-AP,

ZhZ-2-AP

do not affect do not provide

When soldering copper conductors, as well as grounding conductors to the armor and lead sheath of cables, use solder paste of the following composition (in weight parts):

  • Rosin…………………………………….. 10;
  • Animal fat………………………………. 3;
  • Ammonium chloride ………………………… 2;
  • Zinc chloride…………………………….. 1;
  • Water or rectified ethyl alcohol.. 1.

For the same purposes, the following composition is often used for solder paste:

  • Rosin……………………………………… 2.5%;
  • Salo ……………………………………………. 5 %;
  • Zinc chloride……………………………20%;
  • Ammonium chloride …………………………. 2%;
  • Technical Vaseline……………………… 65.5%;
  • Distilled water………………….. 5%.

Flux for soldering aluminum

Brand Compound, % Melting point, °C
Potassium chlorideSodium chlorideLithium chlorideSodium fluorideCryolite grade K-1Magnesium chloride
YOU50–5530–3510–20630
AF-4A5028148» 600
HP503020

VAMI flux is used for terminating wire and cable cores, AF-4A flux is used only for connecting cable cores in couplings.

Fluxes for soldering with soft and semi-hard solders according to electrical standards 0AA.614.017-67 and 0AA.614.028-68

Brand Purpose Compound Cleaning after soldering
Component%
TOTinning and soldering of current-carrying parts made of copper and its alloysPine rosin100Not required
KSP Tinning and soldering of current-carrying parts made of copper and its alloysPine rosin25 Not required
Technical ethyl alcohol grade B75
FPP Tinning and soldering of current-carrying parts made of copper and its alloysPolyester resin grade PA920–30 Not required
Methyl ethyl ketone or ethyl acetate80–70
STUZO-12224-61 Tinning and soldering of current-carrying parts made of copper, nickel and their alloys and parts coated with copper, tin, cadmium, silver and zincPine rosin20–35 Swab or brush soaked in solvent or alcohol
Diethylamine hydrochloride3–5
Triethanolamine1–2
Technical ethyl alcohol grade B76–68
F59A 0AA.614.017-67 Tinning and soldering of aluminum and AMts alloy with each other and with copper and its alloysCadmium borofluoride10 Running hot water or alcohol
Zinc borofluoride3
Ammonium borofluoride5
Triethanolamine82
34A 0AA.614.017-67 Soldering of aluminum and its alloys (melting point 420 °C)Cadmium fluoride50±6 Hot, then cold running water
Lithium chloride32±6
Zinc chloride8±2
Sodium fluoride10±1
LM1 Tinning and soldering of iron-nickel alloys and stainless steelsPine rosin20–35 Swab or brush soaked in solvent or alcohol
Diethylamine hydrochloride3–5
Triethanolamine1–2
Technical ethyl alcohol grade B76–78
F38N Tinning and soldering nichrome between itself and copperDiethylamine hydrochloride25–30 Hot water or a brush dipped in alcohol
Ethylene glycol60–50
Phosphoric acid29–25
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